Sittig's Handbook of Pesticides and Agricultural Chemicals
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Dichloropropenes D:0660
Molecular Formula: C3H4Cl2
Common Formula: CHClQCHCH2Cl
Synonyms: β-Chloroallyl chloride; 3-Chloroallyl chloride; 3-Chloropropenyl chloride; 1,3-D; 1,3-Dichloro-1-propene; 1,3-Dichloro-2-propene; α,β-Dichloropropylene; 1,3- Dichloropropylene; 1,3-Dicloropropeno (Spanish); 1- Propene, 1,3-dichloro-; Propene, 1,3-dichloro-; Telone; Telone II
CAS Registry Number: 563-58-6 (1,1-); 542-75-6; (alt) 8022-76-2 (1,3-); 78-88-6 (2,3-); 26952-23-8 (dichloropropenes); 10061-01-5 (cis-; Z); 10061-02-6 (trans-)
RTECS® Number: UC8310000
UN/NA & ERG Number: UN2047/129
EC Number: 248-134-0 (dichloropropene); 208-826-5 [Annex I Index No.: 602-030-00-5] (1,3-; 8022-76-2); 201- 153-8 [Annex I Index No.: 602-079-00-2] (2,3-; 78-88-6); 233-195-8 [Annex I Index No.: 602-030-00-5] (cis-; Z; 10061-01-5)
Regulatory Authority and Advisory Bodies Carcinogenicity (542-75-6): IARC (technical grade): Animal Sufficient Evidence; Human No Adequate Data, possibly carcinogenic to humans, Group 2B, 1999; NTP (technical grade): 11th Report on Carcinogens, 2004: Reasonably anticipated to be a human carcinogen; NCI: Carcinogenesis Studies (gavage); clear evidence: mouse, rat; NIOSH: Potential occupational carcinogen, See NIOSH Pocket Guide, Appendix A.
US EPA Gene-Tox Program, Positive: Histidine reversion—Ames test.
US EPA, FIFRA 1998 Status of Pesticides: Supported. Air Pollutant Standard Set. See below, “Permissible Exposure Limits in Air” section
Clean Air Act: Hazardous Air Pollutants (Title I, Part A, Section 112).
Clean Water Act: Section 311 Hazardous Substances/RQ 40CFR117.3 (same as CERCLA, see below); 40CFR423, Appendix A, Priority Pollutants; Section 313 Water Priority Chemicals (57FR41331, 9/9/92).
US EPA Hazardous Waste Number (RCRA No.): U084. RCRA, 40CFR261, Appendix 8 Hazardous Constituents. Reportable Quantity (RQ): 100 lb (45.4 kg).
EPCRA Section 313 Form R de minimis concentration reporting level: 0.1%.
US DOT Regulated Marine Pollutant (49CFR172.101, Appendix B).
California Proposition 65 Chemical: Cancer 1/1/89
Canada, WHMIS, Ingredients Disclosure List Concentration 0.1% (CAS: 542-75-6).
Mexico, drinking water, 0.09 mg/L.
European/International Regulations: (1,3-; 542-75-6): Hazard Symbol: T, N; Risk phrases: R10; R20; R24/25; R36/37/38; R43; R65; R50/53; Safety phrases: S1/2; S36/37; S45; S60; S61. (2,3- 78-88-6): Hazard Symbol: F, Xn; Risk phrases: R11; R20/21/22; R37/38; R41; R50/53 ; Safety phrases: S2; S9; S16; S23; 226; S36/37/39; S61 (see Appendix 4). (cis-isomer; 10061-01-5) European/International
Regulations: Hazard Symbol: T, N; Risk phrases: R10; R20; R24/25; R36/37/38; R43; R65; R50/53; Safety phrases: S1/2; S36/37; S45; S60; S61. (trans-isomer; 10061-02-6) Not listed.
WGK (German Aquatic Hazard Class) (1,3-; 78-88-6): 3— Highly water polluting.
trans-isomer: RCRA 40CFR268.48; 61FR15654, Universal Treatment Standards: Wastewater (mg/L), 0.036; Nonwastewater (mg/kg), 18.
RCRA 40CFR264, Appendix 9; TSD Facilities Ground Water Monitoring List. Suggested test method(s) (PQL μg/L): 8010 (5); 8240 (5).
EPCRA Section 313 Form R de minimis concentration reporting level: 0.1%.
European/International Regulations (Z; 10061-01-5): Hazard Symbol: T, N; Risk phrases: R10; R20; R24/25; R36/37/38; R43; R65; R50/53; Safety phrases: S1/2; S36/ 37; S45; S60; S61.
Description: 1,3-Dichloropropene is a colorless to strawcolored liquid with a sharp, sweet, irritating, chloroformlike odor. Molecular weight 5 110.97; Specific gravity (H2O:1) 5 1.21; Boiling point 5 107.7C; 103110C (mixed cis- and trans-isomers); Freezing/Melting point 5 283.8C; Vapor pressure 5 29 mmHg at 20C; Flash point 5 35C. The explosive limits are LEL 5 5.3%; UEL 5 14.5%. Hazard Identification (based on NFPA-704 M Rating System): Health 2, Flammability 3, Reactivity 0. Practically insoluble in water; solubility 5 0.2%. 
Potential Exposure: Compound Description: Agricultural Chemical; Tumorigen, Mutagen; Human Data. Used as a soil fumigant prior to planting crops, such as cotton, sugar beet, potatoes; used in combinations with dichloropropanes as a soil fumigant. Workers engaged in manufacture, formulation, and application of this soil fumigant and nematocide.
MSDS Sheet
MSDS Sheet
MSDS Sheet
MSDS Sheet
MSDS Sheet